Redox ReactionsMedium

Oxidation numbers

Determine the oxidation numbers of each element in: H₂SO₄, K₂Cr₂O₇, NaHCO₃.
Given data
Rules: O = -2, H = +1, alkali metals = +1
Review the theory: Redox
Steps
0 / 3
  1. In H₂SO₄: n.o.(H)=+1, n.o.(O)=-2. Find n.o.(S) knowing sum is 0.
  2. In K₂Cr₂O₇: n.o.(K)=+1, n.o.(O)=-2. Find n.o.(Cr).
  3. In NaHCO₃: n.o.(Na)=+1, n.o.(H)=+1, n.o.(O)=-2. Find n.o.(C).
Full worked solution
  1. In H₂SO₄: n.o.(H)=+1, n.o.(O)=-2. Find n.o.(S) knowing sum is 0.
    2⋅1+x+4⋅(−2)=02\cdot1 + x + 4\cdot(-2) = 0
    2⋅1+x+4⋅(−2)=0→2+x−8=0→x=+62\cdot1 + x + 4\cdot(-2) = 0 \rightarrow 2 + x - 8 = 0 \rightarrow x = \mathbf{+6}. Sulfur.
  2. In K₂Cr₂O₇: n.o.(K)=+1, n.o.(O)=-2. Find n.o.(Cr).
    2⋅1+2x+7⋅(−2)=02\cdot1 + 2x + 7\cdot(-2) = 0
    2⋅1+2x+7⋅(−2)=0→2+2x−14=0→x=+62\cdot1 + 2x + 7\cdot(-2) = 0 \rightarrow 2 + 2x - 14 = 0 \rightarrow x = \mathbf{+6}. Chromium.
  3. In NaHCO₃: n.o.(Na)=+1, n.o.(H)=+1, n.o.(O)=-2. Find n.o.(C).
    1+1+x+3⋅(−2)=01+1+x+3\cdot(-2) = 0
    1+1+x+3⋅(−2)=0→2+x−6=0→x=+41+1+x+3\cdot(-2) = 0 \rightarrow 2 + x - 6 = 0 \rightarrow x = \mathbf{+4}. Carbon.
Result:H₂SO₄: S = +6 — K₂Cr₂O₇: Cr = +6 — NaHCO₃: C = +4.