ElectrochemistryMedium
Nernst equation
Calculate cell potential for Zn²⁺(0.010 M)/Zn: E° = -0.76 V.
Use Nernst: E = E° - (0.0592/n)·log(Q). T = 298 K.
Use Nernst: E = E° - (0.0592/n)·log(Q). T = 298 K.
Given data
E° = -0.76 V[Zn²⁺] = 0.010 Mn = 2 (Zn²⁺ + 2e⁻ → Zn)- Calculate log(Q) where Q = 1/[Zn²⁺] for reduction.
- Calculate E = E° - (0.0592/n)·log(Q).
Full worked solution
- Calculate log(Q) where Q = 1/[Zn²⁺] for reduction.log(100) = 2.
- Calculate E = E° - (0.0592/n)·log(Q).E = -0.76 - (0.0592/2)×2 = -0.76 - 0.0592 = -0.819 V.
Result:E = -0.819 V.